Autocatalysis and self-inhibition: coupled kinetic phenomena in the chlorite-tetrathionate reaction.

Three autocatalysts and self-inhibition in a single reaction: a detailed mechanism of the chlorite-tetrathionate reaction.

The chlorite-tetrathionate reaction has been studied spectrophotometrically in the pH range of 4.65-5.35 at T = 25.0 +/- 0.2 degrees C with an ionic strength of 0.5 M, adjusted with sodium acetate as a buffer component. The reaction is unique in that it demonstrates autocatalysis with respect to the hydrogen and chloride ion products and the key intermediate, HOCl. The thermodynamically most-fa...

Dispersion curves in the diffusional instability of autocatalytic reaction fronts.

A (linear) stability analysis of planar reaction fronts to transverse perturbations is considered for systems based on cubic autocatalysis and a model for the chlorite-tetrathionate reaction. Dispersion curves (plots of the growth rate sigma against a transverse wave-number k) are obtained. In both cases it is seen that there is a nonzero value D0 of D (the ratio of the diffusion coefficients o...

Dispersion curves in the diffusional instability of reaction fronts

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Convective instability in homogeneous and porous media in the chlorite-tetrathionate system

Chiral symmetry breaking in a microscopic model with asymmetric autocatalysis and inhibition.

Asymmetric autocatalysis and inhibition have been proposed as key processes in the spontaneous emergence of chiral symmetry breaking in a prebiotic world. An elementary lattice model is formulated to simulate the kinetics of chiral symmetry breaking via autocatalysis and inhibition in a mixture of prochiral reactants, chiral products, and inert solvent. Starting from a chirally unbiased initial...